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Synthesis and Characterization of Dibenzo[<i>a</i>,<i>f</i>]pentalene: Harmonization of the Antiaromatic and Singlet Biradical Character

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NIAID Data Ecosystem2026-03-10 收录
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Mesityl derivatives of the unknown dibenzopentalene isomer dibenzo­[a,f]­pentalene were synthesized. The molecular geometry and physical properties of dibenzo­[a,f]­pentalene were investigated. Dibenzo­[a,f]­pentalene combines a large antiaromatic and appreciable singlet open-shell character, properties not shared by well-known isomer dibenzo­[a,e]­pentalene.

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2017-10-09
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