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Syntheses and Anion Binding Capabilities of Bis(diarylboryl) Ferrocenes and Related Systems

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Syntheses_and_Anion_Binding_Capabilities_of_Bis_diarylboryl_Ferrocenes_and_Related_Systems/2415961
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Isomeric diborylated ferrocenes featuring 1,1′-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si–F–B bridging motif.
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2016-02-19
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