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Palladium−Indium Iodide-Mediated Allylation and Propargylation of Glyoxylic Oxime Ether and Hydrazone: The Role of Water in Directing the Diastereoselective Allylation

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Palladium_Indium_Iodide_Mediated_Allylation_and_Propargylation_of_Glyoxylic_Oxime_Ether_and_Hydrazone_The_Role_of_Water_in_Directing_the_Diastereoselective_Allylation/3349285
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资源简介:
Allylation and propargylation of glyoxylic oxime ether in the presence of a catalytic amount of palladium(0) complex and indium(I) iodide were studied. Excellent diastereoselectivities in allylation were achieved in the presence of water, although low diastereoselectivities were observed in the absence of water. Propargylation of glyoxylic oxime ether proceeded with good diastereoselectivities in the presence of LiBr or LiCl.
创建时间:
2016-05-07
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