Polysubstituted 2‑Aminopyrrole Synthesis via Gold-Catalyzed Intermolecular Nitrene Transfer from Vinyl Azide to Ynamide: Reaction Scope and Mechanistic Insights
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https://figshare.com/articles/dataset/Polysubstituted_2_Aminopyrrole_Synthesis_via_Gold_Catalyzed_Intermolecular_Nitrene_Transfer_from_Vinyl_Azide_to_Ynamide_Reaction_Scope_and_Mechanistic_Insights/2106691
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资源简介：
A gold-catalyzed intermolecular reaction
of vinyl azides and ynamides
is described. This process presents an efficient and mild approach
to multisubstituted 2-aminopyrroles in good-to-excellent yields. Control
experiments were carried out to distinguish the reactivity between
vinyl azides and the corresponding 2H-azirines. A
plausible reaction mechanism was also proposed according to previous
reports and our preliminary mechanistic studies.
创建时间：
2016-02-12
