Plutonium(IV) Cluster with a Hexanuclear [Pu6(OH)4O4]12+ Core
收藏Figshare2016-02-19 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Plutonium_IV_Cluster_with_a_Hexanuclear_Pu_sub_6_sub_OH_sub_4_sub_O_sub_4_sub_sup_12_sup_Core/2404930
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资源简介：
A mixed hydroxo/oxo plutonium(IV) carboxylate resulting from the hydrolysis and condensation of PuIV in an acidic aqueous solution has been isolated. The structure of Li6[Pu6(OH)4O4(H2O)6(HGly)12]Cl18·10.5H2O (1) consists of a cationic [Pu6(OH)4O4]12+ core that is decorated by glycine ligands. The synthesis, structure, and characterization of the hexanuclear unit, which represents the first example of a PuIV polynuclear complex containing both hydroxo- and oxo-bridging ligands, are described herein.
创建时间：
2016-02-19
