α‑Regioselective Asymmetric [3 + 2] Annulations of Morita–Baylis–Hillman Carbonates with Cyclic 1‑Azadienes and Mechanism Elucidation
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/_Regioselective_Asymmetric_3_2_Annulations_of_Morita_Baylis_Hillman_Carbonates_with_Cyclic_1_Azadienes_and_Mechanism_Elucidation/2074747
下载链接
链接失效反馈官方服务：
资源简介：
An
α-regio-, diastereo-, and enantioselective [3 + 2] annulation
reaction of Morita–Baylis–Hillman carbonates of isatins
and activated alkenes with a bulky electron-withdrawing 1,2-benzoisothiazole
1,1-dioxide or 1,2,3-benzoxathiazine 2,2-dioxide motif is reported,
furnishing an array of spirooxindoles (>19:1 dr, up to >99%
ee) catalyzed
by cinchona-derived tertiary amines. Density functional theory calculation
studies have been conducted to elucidate the originality of the α-regioselective
annulations.
创建时间：
2016-02-12
