Efficient Pd-Catalyzed Dehydrogenative Coupling of P(O)H with RSH: A Precise Construction of P(O)–S Bonds
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https://figshare.com/articles/dataset/Efficient_Pd_Catalyzed_Dehydrogenative_Coupling_of_P_O_H_with_RSH_A_Precise_Construction_of_P_O_S_Bonds/3207706
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资源简介：
A Pd-catalyzed
dehydrogenative phosphorylation of thiols is developed.
A variety of thiols dehydrogenatively couple readily with all three
kinds of P(O)–H compounds, i.e., H-phosphonates, H-phosphinates,
and secondary phosphine oxides, providing a general access to the
valuable phosphorothioates including the P-chiral
compounds. A plausible mechanism is proposed.
创建时间：
2016-05-05
