Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes
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https://figshare.com/articles/dataset/Palladium_Catalyzed_Enantioselective_1_1_Fluoroarylation_of_Aminoalkenes/2127352
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资源简介:
The
development of an enantioselective palladium-catalyzed 1,1-fluoroarylation
of unactivated aminoalkenes is described. The reaction uses arylboronic
acids as the arene source and Selectfluor as the fluorine source to
generate benzylic fluorides in good yields with excellent enantioselectivities.
This transformation, likely proceeding through an oxidative Heck mechanism,
affords 1,1-difunctionalized alkene products.
创建时间:
2016-09-17



