Hierarchical Guest Exchange and Step-by-Step Activation of a Biporous Coordination Framework
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A unique step-by-step activation of the biporous material via formation of the intermediate host–guest complex with a labile ligand has been presented on the example of the metal–organic framework [Zn4(ur)2(ndc)4]. The difference in the chemical environment of channels allows highly selective separation of the mixture of S4N4 and benzene.
创建时间：
2016-02-18
