Rh2(II)-Catalyzed Nitro-Group Migration Reactions: Selective Synthesis of 3-Nitroindoles from β-Nitro Styryl Azides
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https://figshare.com/articles/dataset/Rh_sub_2_sub_II_Catalyzed_Nitro_Group_Migration_Reactions_Selective_Synthesis_of_3_Nitroindoles_from_Nitro_Styryl_Azides/2669236
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Rhodium carboxylate complexes (1 mol %) catalyze the migration of electron-withdrawing groups to selectively produce 3-substituted indoles from β-substituted styryl azides. The relative order of migratorial aptitude for this transformation is ester ≪ amide < H < sulfonyl < benzoyl ≪ nitro.
创建时间：
2016-02-23
