Chemodivergent, Tunable, and Selective Iodine(III)-Mediated Bromo-Functionalizations of Polyprenoids
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https://figshare.com/articles/dataset/Chemodivergent_Tunable_and_Selective_Iodine_III_-Mediated_Bromo-Functionalizations_of_Polyprenoids/5358574
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Mild oxidation of bromides by iodine(III) reagents generated active electrophilic bromination species that were reacted with polyprenoids. By simple and minor variations of an I(III)/Br combination, the reactivity could be selectively steered toward dibromination, oxybromination, or bromocyclization, giving access to a wide array of brominated motifs.
创建时间:
2017-08-31



