Synthesis and Peptide Binding Properties of Methoxypyrrole Amino Acids (MOPAS)
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Methoxypyrrole amino acids (MOPAS) have been prepared and were introduced into small peptides with hairpin structures. The intra- and intermolecular binding properties of this heterocyclic amino acid mimicking a dipeptido β-strand was investigated by NMR titration and X-ray crystal structure analysis. The data reveal a hydrogen bonding pattern that is complementary to a peptide β-sheet.
创建时间：
2016-05-07
