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Convergent Access to Bis-spiroacetals through a Sila-Stetter–Ketalization Cascade

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Convergent_Access_to_Bis_spiroacetals_through_a_Sila_Stetter_Ketalization_Cascade/2375011
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资源简介:
An NHC-catalyzed sila-Stetter reaction between aliphatic acylsilanes and vinylketones bearing silyl ether substituents affords functionalized 1,4-diketones, which upon treatment under acidic conditions leads to the corresponding bis-spiroacetals. The two-step sequence may also be carried out in a one-pot operation leading to high yields of the desired bis-spiroacetals.
创建时间:
2013-09-20
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