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Diastereoisomerically Selective Enantiomerically Pure Titanium Complexes of Salan Ligands: Synthesis, Structure, and Preliminary Activity Studies

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https://figshare.com/articles/dataset/Diastereoisomerically_Selective_Enantiomerically_Pure_Titanium_Complexes_of_Salan_Ligands_Synthesis_Structure_and_Preliminary_Activity_Studies/3280414
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资源简介:
The degree of diastereoselectivity in the wrapping of four new chiral Salan ligands to form chiral-at-metal titanium complexes ranged from mild to perfect as a function of the ligands' N substituents; the enantiomerically pure complexes catalyzed the addition of diethyl zinc to benzaldehyde in 73−76% enantiomeric excess.
创建时间:
2016-05-05
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