Metallo-Cryptophanes Decorated with Bis-N-Heterocyclic Carbene Ligands: Self-Assembly and Guest Uptake into a Nonporous Crystalline Lattice
收藏NIAID Data Ecosystem2026-03-09 收录
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资源简介：
Pd3L2 metallo-cryptophane cages with cyclotriveratrylene-type L ligands can be stabilized by use of a bis-N-heterocyclic carbene as an auxiliary cis-protecting ligand, while use of more common protecting chelating ligands such as ethylenediamine saw a Pd3L2 to Pd6L8 rearrangement occur in solution. The crystalline Pd3L2 complexes act as sponges, taking up 1,2-dichorobenzene or iodine in a single-crystal-to-single-crystal fashion despite not exhibiting conventional porosity.
创建时间：
2015-12-17
