Double Dehydrogenation of Primary Amines to Nitriles by a Ruthenium Complex Featuring Pyrazole Functionality
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https://figshare.com/articles/dataset/Double_Dehydrogenation_of_Primary_Amines_to_Nitriles_by_a_Ruthenium_Complex_Featuring_Pyrazole_Functionality/6734588
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资源简介：
A ruthenium(II)
complex bearing a naphthyridine-functionalized
pyrazole ligand catalyzes oxidant-free and acceptorless selective
double dehydrogenation of primary amines to nitriles at moderate temperature.
The role of the proton-responsive entity on the ligand scaffold is
demonstrated by control experiments, including the use of a N-methylated
pyrazole analogue. DFT calculations reveal intricate hydride and proton
transfers to achieve the overall elimination of 2 equiv of H2.
创建时间：
2018-07-02
