Bonding and Reactivity of a Dicopper(I) μ‑Boryl Cation
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https://figshare.com/articles/dataset/Bonding_and_Reactivity_of_a_Dicopper_I_Boryl_Cation/2084413
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资源简介：
A siloxide-bridged dicopper(I) cation
reacts with bis(catecholato)diboron
to form the boryl-bridged dicopper cation {[(SIDipp)Cu]2(μ-Bcat)}+ (SIDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene;
cat = 1,2-C6H4O2). The solid-state
structure shows an acute angle about the boryl, with a short intermetallic
distance. Density functional theory calculations indicate a small
but significant copper–copper bond order. The boryl-bridged
cation deprotonates phenylacetylene and reacts with methanol to form
a hydride-bridged dicopper cation.
创建时间：
2016-02-12
