One-Pot Synthesis of Substituted 2,2′-Bipyrroles. A Straightforward Route to Aryl Porphycenes
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A one-pot reaction for the synthesis of 4,4′-diaryl- and 4,4′-diheteroaryl-substituted 2,2′-bipyrroles is described. The new methodology is based on the oxidative coupling of a 2-trimethylstannylated pyrrole and does not require chromatography. These 2,2′-bipyrroles can be used as precursors in a expeditious synthesis of 2,7,12,17-tetraaryl-porphycenes.
创建时间：
2009-01-01
