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Carbocyclization Cascades of Allyl Ketenimines via Aza-Claisen Rearrangements of N-Phosphoryl-N-allyl-ynamides

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Figshare2016-02-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Carbocyclization_Cascades_of_Allyl_Ketenimines_via_i_Aza_i_Claisen_Rearrangements_of_i_N_i_Phosphoryl_i_N_i_allyl_ynamides/2533669
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资源简介:
A series of carbocyclization cascades of allyl ketenimines initiated through a thermal aza-Claisen rearrangement of N-phosphoryl-N-allyl ynamides is described. Interceptions of the cationic intermediate via Meerwein–Wagner rearrangements and polyene-type cyclizations en route to fused bi- and tricyclic frameworks are featured.
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2016-02-21
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