A Dinuclear Ruthenium(II) Chelating Amido Complex: Synthesis, Characterization, and Coupling Reaction with Carbon Monoxide
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https://figshare.com/articles/dataset/A_Dinuclear_Ruthenium_II_Chelating_Amido_Complex_Synthesis_Characterization_and_Coupling_Reaction_with_Carbon_Monoxide/3331840
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资源简介：
[Cp*RuCl]4 (Cp* = η5-C5Me5) reacts with 2
equiv of dilithium 2,3-naphthalenediamide to afford the
dinuclear bridging amido complex [(Cp*Ru)2{μ2-(NH)2C10H6}] (1b) in moderate yield. Treatment of 1b with
CO (1 atm) resulted in the incorporation of three
molecules of CO into the diruthenium core to give the
carbamoyl amido bis(carbonyl) complex [Cp*Ru(μ2-CO){μ2-2,3-(CONH)(NH)C10H6}RuCp*(CO)] (4).
创建时间：
2016-05-06
