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Reactivity of (3-Iminophosphine)palladium(II) Complexes: Evidence of Hemilability

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https://figshare.com/articles/dataset/Reactivity_of_3_Iminophosphine_palladium_II_Complexes_Evidence_of_Hemilability/2861488
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Several palladium(II) 3-iminophosphine complexes were synthesized in moderate to high yield. With relevance to many palladium-catalyzed coupling reactions, these complexes incorporate a wide variety of ligands, including amines, alkyls, allyls, and triflates. The presence of both η1- and η2-coordination modes demonstrates the hemilability of the 3-iminophosphine ligand class, as determined by X-ray crystallography and NMR spectroscopy.
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2016-02-26
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