Rhodium Complexes Bearing PAlP Pincer Ligands
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https://figshare.com/articles/dataset/Rhodium_Complexes_Bearing_PAlP_Pincer_Ligands/6427610
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资源简介：
We
report rhodium complexes bearing PAlP pincer ligands with an
X-type aluminyl moiety. IR spectroscopy and single-crystal X-ray diffraction
analysis of a carbonyl complex exhibit the considerable σ-donating
ability of the aluminyl ligand, whose Lewis acidity is confirmed through
coordination of pyridine to the aluminum center. The X-type PAlP–Rh
complexes catalyze C2-selective monoalkylation of pyridine with alkenes.
创建时间：
2018-06-04
