A Ruthenium(II) Complex Stabilized by a Highly Fluorinated PCP Pincer Ligand
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https://figshare.com/articles/dataset/A_Ruthenium_II_Complex_Stabilized_by_a_Highly_Fluorinated_PCP_Pincer_Ligand/3268762
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资源简介：
A novel Ru(II) complex containing an electron-poor, highly fluorinated PCPArF pincer ligand
has been synthesized in good yield via a transcyclometalation reaction. The complex has
been fully characterized by elemental analysis, 1D and 2D NMR techniques, UV−vis
spectroscopy, and cyclic voltammetry. Single-crystal X-ray structural analysis and DFT
calculations were performed. The structural features and electronic properties of the
remarkably stable PCPArF−Ru(II) complex 4 have been investigated and show unanticipated
differences compared to its protio analogue.
创建时间：
2016-05-05
