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Synthesis and Crystal Structure of NZP-Type Thorium−Zirconium Phosphate

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NIAID Data Ecosystem2026-03-06 收录
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Microcrystals of Th1/4Zr2(PO4)3 were synthesized by thermal treatment (900 °C) of the material obtained using sol−gel technology (including organic complex formation and etherification). Their structure [hexagonal, P3̅c, a = b = 8.7311(4) Å, c = 23.309(2) Å] includes the three-dimensional [Zr2(PO4)3]− NASICON-type network and extraframework 6-fold-coordinated thorium(IV) cations.

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2016-02-25
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