Reactivity of a Disilylene [{PhC(NBut)2}Si]2 toward Bromine: Synthesis and Characterization of a Stable Monomeric Bromosilylene
收藏acs.figshare.com2023-06-06 更新2025-01-21 收录
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https://acs.figshare.com/articles/dataset/Reactivity_of_a_Disilylene_PhC_NBu_sup_t_sup_sub_2_sub_Si_sub_2_sub_toward_Bromine_Synthesis_and_Characterization_of_a_Stable_Monomeric_Bromosilylene/2798956/1
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The reaction of the disilylene [{PhC(NBut)2}Si]2 (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBut)2}SiBr] (2). The result shows that the SiI−SiI bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined.
与1当量溴在甲苯中反应的硅二烯[{PhC(NBut)2}Si]2(1)生成了新颖的单体溴硅二烯[{PhC(NBut)2}SiBr](2)。结果表明，化合物1中的SiI-SiI键被溴所断裂。已确定化合物2的X射线结构。
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ACS Publications
