Boraphosphaalkene Synthesis via Phosphaalkyne Insertion into 9‑Borafluorene
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https://figshare.com/articles/dataset/Boraphosphaalkene_Synthesis_via_Phosphaalkyne_Insertion_into_9_Borafluorene/6279185
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资源简介:
The reaction of 1-adamantylphosphaalkyne
with 9-phenyl-9-borafluorene
resulted in the insertion of the PC unit into the endocyclic
B–C bond, generating a seven-membered 1,3-boraphosphaalkene.
The mechanism was investigated computationally, indicating that the
reaction proceeds via a bond metathesis pathway.
创建时间:
2018-05-22



