Phosphole-Containing Hybrid Calixpyrroles: New Multifunctional Macrocyclic Ligands for Platinum(II) Ions
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https://figshare.com/articles/dataset/Phosphole_Containing_Hybrid_Calixpyrroles_New_Multifunctional_Macrocyclic_Ligands_for_Platinum_II_Ions/3075466
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资源简介:
Phosphole-containing hybrid calixpyrroles have been
prepared by acid-promoted condensation reactions. σ3-Calix[1]phosphole[1]thiophene[2]pyrrole reacts with PtCl2(COD) to
afford an unusual type of macrocyclic Pt(II)−monophosphine
complex bearing a η3-cyclooctadienyl ligand, in which the
phosphole and pyrrole units bind the Pt−Cl moiety through
cooperative, noncovalent bonding interactions.
创建时间:
2016-03-01



