Molecular CHEVREL-like Clusters [(RhPPh3)6(μ3‑Se)8] and [Pd6(μ3‑Te)8]4–
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https://figshare.com/articles/dataset/Molecular_CHEVREL_like_Clusters_RhPPh_sub_3_sub_sub_6_sub_sub_3_sub_Se_sub_8_sub_and_Pd_sub_6_sub_sub_3_sub_Te_sub_8_sub_sup_4_sup_/2186110
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[(RhPPh3)6(μ3-Se)8]·0.5en (1; en = ethane-1,2-diamine), obtained by the reaction of [Pb2Se3]2– anions with [Rh(PPh3)3Cl] in en, represents the first compound comprising a molecular [Rh6] octahedron with all faces capped by Se atoms. Analogous treatment of [Pb2Te3]2– with [Pd(PPh3)2Cl2] yielded [Li4(en)10][Pd6(μ3-Te)8] (2), the first compound exhibiting a molecular, chalcogen-capped [Pd6] aggregate. Besides syntheses and structures of the title compounds, we report quantum-chemical calculations to understand the electronic properties of these molecular CHEVREL-like complexes.
创建时间：
2016-02-14
