Highly Stereoselective Intermolecular Oxy-Michael Addition Reaction to α,β-Unsaturated Malonate Esters
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https://figshare.com/articles/dataset/Highly_Stereoselective_Intermolecular_Oxy_Michael_Addition_Reaction_to_Unsaturated_Malonate_Esters/3341413
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资源简介：
The highly diastereoselective oxy-Michael addition of the “naked” anion of (6S)-methyl δ lactol to alkylidiene-, arylidene-, and heteroarylidenemalonate derivatives leading to the direct formation of THP*-protected β-hydroxy ester derivatives is described. Subsequent acid-mediated
deprotection affords the enantioenriched aldol products in quantitative yields.
创建时间：
2016-05-07
