Formation of [NiIII(κ1‑S2CH)(P(o‑C6H3‑3-SiMe3‑2-S)3)]− via CS2 Insertion into Nickel(III) Hydride Containing [NiIII(H)(P(o‑C6H3‑3-SiMe3‑2-S)3)]−
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Insertion of CS2 into the thermally unstable nickel(III) hydride [PPN][Ni(H)(P(o-C6H3-3-SiMe3-2-S)3)] (1), freshly prepared from the reaction of [PPN][Ni(OC6H5)P(C6H3-3-SiMe3-2-S)3] and 4,4,5,5-tetramethyl-1,3,2-dioxaborolane (HBpin; pin = OCMe2CMe2O) in tetrahydrofuran at −80 °C via a metathesis reaction, readily affords [PPN][NiIII(κ1-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)] (2) featuring a κ1-S2CH moiety.
创建时间：
2016-02-22
