TMCL_bOG_TMAOH_DSS

This dataset contains NMR spectra obtained for the sample -TMCL_bOG_TMAOH_DSS Nucleus: 13C NMR Solvent: H2O+D2O NMR Probe: H8609_0043 (PH MAS 500WB BL4 X/Y/H DVT) NMR Pulse Sequence: null Temperature: 295.9979 Observed Frequency: 125.78746 Magnetic Field Strength: 11.747332789100614 Number of Scans: 2048 NMR Pulse Sequence: C90.hpdec Spectral Width: 248.416800520177 Number of Data Points: 3120 Relaxation Delay: 5 Observed Frequency: 125.79664473 Nucleus: 13C NMR Solvent: H2O+D2O NMR Probe: H8609_0043 (PH MAS 500WB BL4 X/Y/H DVT) NMR Pulse Sequence: null Temperature: 296.0139 Observed Frequency: 125.78746 Magnetic Field Strength: 11.747332789100614 Number of Scans: 2048 NMR Pulse Sequence: NEA_ineptrd Spectral Width: 150.558198668802 Number of Data Points: 1892 Relaxation Delay: 5 Observed Frequency: 125.79450409776 Nucleus: 1H NMR Solvent: H2O+D2O NMR Probe: H8609_0043 (PH MAS 500WB BL4 X/Y/H DVT) NMR Pulse Sequence: null Temperature: 295.9999 Observed Frequency: 500.248 Magnetic Field Strength: 11.749122218330188 Number of Scans: 16 NMR Pulse Sequence: onepulse Spectral Width: 19.9900077947037 Number of Data Points: 3006 Relaxation Delay: 10 Observed Frequency: 500.24993 Nucleus: 31P NMR Solvent: H2O+D2O NMR Probe: H8609_0043 (PH MAS 500WB BL4 X/Y/H DVT) NMR Pulse Sequence: 1d Temperature: 295.9903 Observed Frequency: 202.504102 Magnetic Field Strength: 11.745385617451017 Number of Scans: 256 NMR Pulse Sequence: NEA_zg30bbdec Spectral Width: 201.284225443572 Number of Data Points: 8148 Relaxation Delay: 5 Observed Frequency: 202.5040436 Nucleus: 31P NMR Solvent: H2O+D2O NMR Probe: H8609_0043 (PH MAS 500WB BL4 X/Y/H DVT) NMR Pulse Sequence: 1d Temperature: 296.0007 Observed Frequency: 202.504102 Magnetic Field Strength: 11.745385617451017 Number of Scans: 2048 NMR Pulse Sequence: NEA_zg30bbdec Spectral Width: 201.284225443572 Number of Data Points: 4072 Relaxation Delay: 5 Observed Frequency: 202.5040436 Nucleus: 13C,1H NMR Solvent: H2O+D2O NMR Probe: H8609_0043 (PH MAS 500WB BL4 X/Y/H DVT) NMR Pulse Sequence: null Temperature: 295.9898 Observed Frequency: 125.78746,500.248 Magnetic Field Strength: 11.747332789100614 Number of Scans: 256 NMR Pulse Sequence: NEA_RPDLF Spectral Width: 150.558198668802,4.99752988789391 Number of Data Points: 1892,32 Relaxation Delay: 6 Observed Frequency: 125.79450409776,500.2471333

TMCL (26.2mg, 1.0 eq.), β-OG (6mg, 1.0eq.), DSS (0.25mg, 0.06eq.) and TMA OHx5H2O
(7.4mg, 2.0eq.) were dissolved with 1ml chloroform:methanol (2:1, v/v) in an eppendorf vial. The
solvent was evaporated at 40°C under a constant stream of argon and the predried sample was
freeze-dried over night. 20.5µl degassed water was added and the Eppendorf was stored at 40°C
for two days. Lost water was added and the sample was mixed thoroughly with a steel rod. After
another two days of equilibration the sample was again mixed before packing the insert.