Novel Metalloreagent Cp(CO)<sub>2</sub>FeP(Se)(OR)<sub>2</sub> Produced from P−Se Bond Cleavage in the Thermal Reaction of [CpFe(CO)<sub>2</sub>]<sub>2</sub> with Phosphor-1,1-diselenolates
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The reaction of [CpFe(CO)2]2 with NH4Se2P(OR)2 yields a novel reagent Cp(CO)2FeP(Se)(OR)2, which has demonstrated coordination properties at the Se center to form heterometallic clusters as well as reactivity at the Se site toward C-based electrophiles.
创建时间:
2006-10-30



