Crystal structure of μ-oxido-1,1′ κ 2 O: O-bis{tetra- μ-oxido-1:2 κ 2 O: O;1:3 κ 2 O: O;2:3 κ 4 O: O-tris[1,2,3( η 5)-pentamethylcyclopentadienyl]- trianglo-trititanium(IV)}

Name: Crystal structure of μ-oxido-1,1′ κ 2 O: O-bis{tetra- μ-oxido-1:2 κ 2 O: O;1:3 κ 2 O: O;2:3 κ 4 O: O-tris[1,2,3( η 5)-pentamethylcyclopentadienyl]- trianglo-trititanium(IV)}
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Published: 2025-11-12 09:15:22
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The title polynuclear organometallic titanium(IV) oxide, [{Ti3( η 5-C 5Me 5) 3( μ-O) 4} 2( μ-O)], exhibits two Ti3O 4 cores bridged by an O atom located on a twofold axis. All metal centres present the typical three-legged piano-stool coordination environment, where one site is occupied by a pentamethylcyclopentadienyl ligand linked in an η 5-coordination fashion, while three bridging O atoms fill the other three sites.

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2019-03-05

Crystal structure of μ-oxido-1,1′ κ 2 O: O-bis­{tetra- μ-oxido-1:2 κ 2 O: O;1:3 κ 2 O: O;2:3 κ 4 O: O-tris­[1,2,3( η 5)-penta­methyl­cyclo­penta­dien­yl]- trianglo-trititanium(IV)}

Crystal structure of μ-oxido-1,1′ κ 2 O: O-bis{tetra- μ-oxido-1:2 κ 2 O: O;1:3 κ 2 O: O;2:3 κ 4 O: O-tris[1,2,3( η 5)-pentamethylcyclopentadienyl]- trianglo-trititanium(IV)}