Highly Enantioselective Synthesis of Tetrahydrocarbolines via Iridium-Catalyzed Intramolecular Friedel–Crafts Type Allylic Alkylation Reactions
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https://figshare.com/articles/dataset/Highly_Enantioselective_Synthesis_of_Tetrahydrocarbolines_i_via_i_Iridium_Catalyzed_Intramolecular_Friedel_Crafts_Type_Allylic_Alkylation_Reactions/2346178
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A highly enantioselective synthesis of substituted tetrahydrocarbolines via Ir-catalyzed Friedel–Crafts type intramolecular asymmetric allylic alkylation of 2-indolyl allyl carbonates has been developed. This strategy features excellent chemoselectivity and enantioselectivity, mild reaction conditions, and an easily accessed chiral ligand.
创建时间：
2016-02-18
