1,4-Di(1,2,3-triazol-1-yl)butane as Building Block for the Preparation of the Iron(II) Spin-Crossover 2D Coordination Polymer
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https://figshare.com/articles/dataset/1_4_Di_1_2_3_triazol_1_yl_butane_as_Building_Block_for_the_Preparation_of_the_Iron_II_Spin_Crossover_2D_Coordination_Polymer/3280378
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资源简介:
The novel bidentate ligand 1,4-di(1,2,3-triazol-1-yl)butane (bbtr)
reacts with Fe(ClO4)2·6H2O to form the 2D coordination polymer
with (3,6) network topology. The {[Fe(bbtr)3](ClO4)2}∞ represents
an example of spin-crossover material based on 1,2,3-triazole as
donor group, and displays an abrupt spin transition accompanied
by a thermal hysteresis loop (T1/2↓ = 101 K and T1/2↑ = 109 K).
创建时间:
2016-05-05



