Bis(methimazolyl)silyl Complexes of Ruthenium
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https://figshare.com/articles/dataset/Bis_methimazolyl_silyl_Complexes_of_Ruthenium/2790382
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资源简介:
The new bis(methimazolyl)silane PhSiH(mt)2 (mt = methimazolyl), obtained from methimazole (Hmt) and phenyldichlorosilane, reacts with [Ru(η4-C8H12)(η6-C8H10)] in refluxing tetrahydrofuran to provide the cis and trans isomers of [Ru{κ3Si,S,S′-SiPh(mt)2}]. The structurally characterized trans isomer crystallizes directly from THF but on dissolution in CH2Cl2 converts exclusively to the cis isomer.
创建时间:
2010-02-22



