Regio- and Stereoselective Synthesis of 2‑Amino-dienes via Decarboxylative Amination of 4‑(Ethoxycarbonyl)-2,3-allenols by TsNCO
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https://figshare.com/articles/dataset/Regio_and_Stereoselective_Synthesis_of_2_Amino_dienes_via_Decarboxylative_Amination_of_4_Ethoxycarbonyl_2_3_allenols_by_TsNCO/2232937
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资源简介：
A metal-free decarboxylative amination
of 4-(ethoxycarbonyl)-2,3-allenols
by TsNCO via base-induced aza-Michael addition/elimination has been
developed. A variety of substituted N-tosyl 1,3-dien-2-yl
amines were obtained in good yields and excellent regio- and stereoselectivity.
Moreover, this transformation could be applied in preparation of 2-amino-trienes.
创建时间：
2014-11-21
