Hydrazone as the Directing Group for Ir-Catalyzed Arene Diborylations and Sequential Functionalizations
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https://figshare.com/articles/dataset/Hydrazone_as_the_Directing_Group_for_Ir_Catalyzed_Arene_Diborylations_and_Sequential_Functionalizations/2540590
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资源简介:
The use of hemilabile pyridine–hydrazone N,N-ligands
allows
the highly selective Ir-catalyzed ortho,ortho′-directed diborylation
of aromatic N,N-dimethylhydrazones
in near-quantitative yields. One-pot sequential Suzuki–Miyaura
cross-coupling with different aryl bromides provides a short entry
to unsymmetrically substituted 2,6-diarylbenzaldehyde derivatives.
创建时间:
2016-02-21



