Synthesis of Dinuclear Boron Complexes of Sulfinylcalix[4]arenes: Syn/Anti Stereocontrol by the Arrangement of the Sulfinyl Functions
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Stereocontrol in the synthesis of dinuclear metal complexes of sulfinylcalix[4]arenes 2 has been achieved by the arrangement of sulfinyl functionalities. Thus, the treatment of the rtct isomer of 2 (2rtct) with an excess of Et3B affords syn dinuclear boron complex 4, while a similar treatment of rctt and rcct isomers 2rctt and 2rcct yields anti dinuclear complexes 5 and 6, respectively.
创建时间：
2016-02-27
