Metallaboratranes: The M→B Dative Bond as a Ligand Activating Function in the Phosphaboration of Carbon Monosulfide†
收藏Figshare2007-07-30 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Metallaboratranes_The_M_B_Dative_Bond_as_a_Ligand_Activating_Function_in_the_Phosphaboration_of_Carbon_Monosulfide_sup_sup_/12065835
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The reaction of Na[H2B(mt)2] (mt = methimazolyl) with [RhCl(CO)(PPh3)2] proceeds via simple metathesis to provide the complex [Rh(CO)(PPh3){H2B(mt)2}]; however, with [RhCl(CS)(PPh3)2] C,C-phosphaboration of the thiocarbonyl ligand occurs, with formation of the novel cage complex [RhH(PPh3){η2(C,S),κ2S‘,S‘ ‘-SC(PPh3)BH(mt)2}].
创建时间：
2007-07-30
