Highly Stereoselective Aldol Reaction for the Synthesis of γ-Lactones Starting from Tartaric Acid
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A simple stereoselective process for the synthesis of highly substituted γ-lactones was developed based on aldol reactions between the enolate of dioxanes derived from tartaric acid and aldehydes. A range of aromatic and aliphatic aldehydes were reacted, in most cases achieving good yields and stereoselectivity. The limitations of this reaction were identified and a transition state is proposed.
创建时间：
2016-05-06
