Protonation Equilibrium and Hydrogen Production by a Dinuclear Cobalt–Hydride Complex Reduced by Cobaltocene with Trifluoroacetic Acid
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https://figshare.com/articles/dataset/Protonation_Equilibrium_and_Hydrogen_Production_by_a_Dinuclear_Cobalt_Hydride_Complex_Reduced_by_Cobaltocene_with_Trifluoroacetic_Acid/2365975
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资源简介：
A dinuclear
Co complex with bis(pyridyl)pyrazolato (bpp–) and
terpyridine (trpy) ligands, [CoIII2(trpy)2(μ-bpp)(OH)(OH2)]4+ (14+), undergoes three-electron reduction by cobaltocene
in acetonitrile to produce 1+, which is in
the protonation equilibrium with the CoIICoIII–hydride complex, and the further protonation of the hydride
by trifluoroacetic acid yields hydrogen quantitatively. The kinetic
study together with the detection of the CoIICoIII-hydride complex revealed the mechanism of the hydrogen production
by the reaction of 1+ with trifluoroacetic
acid.
创建时间：
2016-02-18
