Ferromagnetic Disklike Mn<sup>IV</sup>Mn<sup>II</sup><sub>3</sub>Na<sup>I</sup><sub>3</sub> Heptanuclear Complex with a <i>S</i> = 9 Ground State
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The wheel-shaped heptanuclear cluster complex {[Mn4Na3(thmp)2(acac)6(H2O)6]CH3COO}·4H2O is the first heterometallic mixed-valent disklike compound with apical alkali-metal ions. The weak ferromagnetic interaction between the central Mn4+ ion and the peripheral Mn2+ ones leads to a high-spin ground state (S = 9).
创建时间:
2009-02-02



