Transition metal complexes containing ligands featuring three-coordinate, halide-functionalized gallium or indium donors represent key precursors to unsaturated cationic species of the type [LnM(EX)]+
In early reports, the boron atom of the anionic borido complexes [{(η5-C5H4R)(OC)2Mn}2B]− (R = H, Me) showed nucleophilic behavior in the presence of electrophiles such as methyl iodide and group 11
This is a physical chemical entity[CHEBI_24431] associated with a molecule[CHEBI_25367]. The molecule[CHEBI_25367] can be described by the following structural desciptors[cheminf_000085]: InChI desc
Treatment of the bis-acetylide zirconocene complexes (RCp)2Zr(CC−SiMe3)2 (8a, R = CH3; 8b, R = tert-butyl) with HB(C6F5)2 results in the formation of the five-membered organometallic zirconacycloalle