A Heterobimetallic Rhodium(I)−Ruthenium(II) Catalyst for the Oppenauer-Type Oxidation of Primary and Secondary Alcohols under Mild Conditions
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https://figshare.com/articles/dataset/A_Heterobimetallic_Rhodium_I_Ruthenium_II_Catalyst_for_the_Oppenauer_Type_Oxidation_of_Primary_and_Secondary_Alcohols_under_Mild_Conditions/3330361
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资源简介：
A heterobimetallic complex, in which a RuCl2(acetone)(PPh3)2 fragment is connected via three chloro
bridges to a (η4-C4Ph4CO)RhCl fragment, has been
identified as a potent catalyst precursor for the Oppenauer-type oxidation of alcohols. With 0.1−0.5 mol %
of this complex and K2CO3 as the cocatalyst, it is possible
to oxidize secondary and primary alcohols at room
temperature using acetone as the solvent and oxidation
agent.
创建时间：
2004-08-02
