Stereoselective Alkylation of (<i>S</i>)‑<i>N</i>‑Acyl-4-isopropyl-1,3-thiazolidine-2-thiones Catalyzed by (Me<sub>3</sub>P)<sub>2</sub>NiCl<sub>2</sub>
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The structurally simple (Me3P)2NiCl2 complex catalyzes SN1-type alkylations of chiral N-acyl thiazolidinethiones with diarylmethyl methyl ethers and other stable carbenium cations. The former can contain a variety of functional groups and heteroatoms at the α-position. The resultant adducts are isolated as single diastereomers in high yields and can be converted into enantiomerically pure derivatives in a straightforward manner.
创建时间：
2016-02-13
