Direct Aziridination of Nitroalkenes Affording N‑Alkyl‑C‑nitroaziridines and the Subsequent Lewis Acid Mediated Isomerization to β‑Nitroenamines
收藏Figshare2017-09-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Direct_Aziridination_of_Nitroalkenes_Affording_i_N_i_Alkyl_i_C_i_nitroaziridines_and_the_Subsequent_Lewis_Acid_Mediated_Isomerization_to_Nitroenamines/5425804
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资源简介：
A mild and highly diastereoselective one-pot synthesis of trans-N-alkyl-C-nitroaziridines was achieved by treatment of nitroalkenes with aliphatic amines and N-chlorosuccinimide. Treatment of the obtained aziridines with a Lewis acid resulted in a facile ring opening reaction, accompanied by rearrangement and isomerization into functionalized (Z)-β-nitroenamines.
创建时间：
2017-09-20
