Direct Aziridination of Nitroalkenes Affording N‑Alkyl‑C‑nitroaziridines and the Subsequent Lewis Acid Mediated Isomerization to β‑Nitroenamines
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A mild and highly diastereoselective one-pot synthesis of trans-N-alkyl-C-nitroaziridines was achieved by treatment of nitroalkenes with aliphatic amines and N-chlorosuccinimide. Treatment of the obtained aziridines with a Lewis acid resulted in a facile ring opening reaction, accompanied by rearrangement and isomerization into functionalized (Z)-β-nitroenamines.
创建时间：
2017-09-20
