Iridium Abnormal N-Heterocyclic Carbene Hydrides via Highly Selective C−H Activation
收藏NIAID Data Ecosystem2026-03-06 收录
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Imidazoliums with proximal phosphines undergo C−H oxidative addition on [Ir(COD)Cl]2 to give iridium(III) abnormal carbene hydrides. The effects of the length of the linker between the imidazolium and the phosphine are systematically studied. These C−H activation products can undergo base-promoted H−Cl reductive elimination to afford the corresponding Ir(I) abnormal NHC complexes.
创建时间：
2016-06-03
