Ag(nic)<sub>2</sub> (nic = Nicotinate): A Spin-Canted Quasi-2D Antiferromagnet Composed of Square-Planar <i>S</i> = <sup>1</sup>/<sub>2</sub> Ag<sup>II</sup> Ions
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Square-planar S = 1/2 AgII ions in polymeric Ag(nic)2 are linked by bridging nic monoanions to yield 2D corrugated sheets. Long-range magnetic order occurs below TN = 11.8(2) K due to interlayer couplings that are estimated to be about 30 times weaker than the intralayer exchange interaction.
创建时间:
2016-02-22



